Evan Agostini, AP
The event, which will be held on June 5 at the Nashville Gun Club, will include 15 teams, pairing professional shooters with celebrities such as Luke Bryan, Montgomery Gentry, Craig Campbell, Josh Gracin, JT Hodges and the Warren Brothers.
Proceeds from the event will go toward efforts to improve the lives of military service members who are suffering from brain injuries and post-traumatic stress disorder.
The Brothers of the Sun tour begins June 2 in Tampa, Fla., and the two singer-songwriters are already enjoying spending time together as they prepare to hit the road.
"It's been a long time since we've played on stage together and the chemistry and excitement is just so natural," Kenny noted after their first joint rehearsal. "It's going to be a dream come true to have our years of friendship come together on stage for what will be one unpredictable, loud, hell of a summer, and I can't wait."
Keep track of Kenny and Tim's concert schedule here.
See More on Tim & Kenny's Brothers of the Sun Tour