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Vince, who hosted the ceremony for a record 12 times, will be performing with Kelly Clarkson. The pair trade vocals on the tune "Don't Rush," which will be included on the Female Vocalist of the Year nominee's upcoming album, Greatest Hits -- Chapter 1.
The new performers join the previously announced Jason Aldean, Dierks Bentley, Luke Bryan, Kenny Chesney, Eric Church, Eli Young Band, Brantley Gilbert, Faith Hill, Lady Antebellum, Miranda Lambert, Little Big Town, Tim McGraw, Brad Paisley, Blake Shelton, Taylor Swift, the Band Perry, Carrie Underwood, Taylor Swift and Zac Brown Band.
Brad Paisley and Carrie Underwood are hosting the show for the fifth consecutive time. Winners will be announced during the live telecast on Thursday, Nov. 1 beginning at 8:00 PM ET on ABC.